Total entropy change, also called the entropy change of the universe, is the sum of the entropy change of a system and of its surroundings:Īccording to the second law of thermodynamics, the entropy of the universe, S univ must always increase for a spontaneous process, that is, DS univ>0.įree Energy and Free Energy Change -the Gibbs free energy, G, is used to describe the spontaneity of a process. The direction of spontaneous change is the direction in which total entropy increases.
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